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What year is your C10 and what style tank selector do you currently have. The valve you have looks like a standard pig tail and connector for an '87 TBI dual tank truck. Studying the wiring diagram may help you figure out which wires are which.
Do you have a '76 C10 with factory dual tanks? How many terminals on the back of the dash switch?
The motorized valve requires a DPDT switch. The OEM factory switch in the dash is a hybrid DP(S/D)T configuration. To make the valve work you will need to insert a SPDT ISO relay not shown on the diagram that came with the valve. The SPDT relay will be controlled by the side of the switch that has only two terminals.
If you are willing to replace the dash switch, use the 1987-up rocker switch for TBI and dispense with a relay. I suggest the TBI rocker switch because it is not a momentary contact, so you don't need to hold it down if the valve rack is sluggish. A plus is that the diagram that you received with the new valve applies directly to the later model switch.You may find it beneficial to peruse the topics, Dual Tanks Theory of operation and Fuel selector switch.
Yes, with a caveat. The TBI switch has only 4-terminals because it is internally wired with the cross X.