Its hard to nail this kind of thing down sometimes. Your misfire may be unrelated, maybe not. Does your truck puff out a little smoke when you start it? What about under load or when you get on the gas sitting still? Are your plug wires (particularly that one) in good shape? If it really is carbon soot and not oil then I would say your likely not getting good spark to that plug. You might try the ol' rpm drop test. Start the engine and pull that plug wire off while its running and note the rpm drop. Pull one of the others and compare the rpm drop. If it doesn't drop much when you pull that wire then that cylinder's not doing its share.