You can use Mark IV heads on a V block but you have to use special head gaskets, voodoo and be very careful. It's not a bad motor, you just need to read up on it and learn about the differences.
Does the block use a 1 pc or 2 pc rear main? 2 pc is Mark IV, 1 pc is Mark V or VI.
Btw, Mark V = no mechanical fuel pump boss, electric only.