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I've used POR15 for years an never had an issue with it adhering to the frame. I tried Chassis Saver by the recommendation of Blazin here and all I can assess is that it's less expensive but works the same. Don't go crazy just shoot it on there. If you truly want a better finished result get it powder coated.
never heard of the nitrogen, or argon trick. Sounds right though. I will have to try that out.